Patent · US Expired

Rapid reversible intercalation of lithium into carbon secondary battery electrodes

US5422203A · kind A · utility

20Cited by
8References
7Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 28, 1992
Grant dateJun 6, 1995
Priority date
Expiry dateSep 28, 2012

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02E60/10
  • WIPO fieldElectrical machinery, apparatus, energy
  • WIPO sectorElectrical engineering

Abstract

Irreversible loss of lithium during the initial discharge cycle of secondary batteries with carbon intercalation electrodes is substantially reduced by employing as the cell electrolyte a non-aqueous solution of LiPF.sub.6 in a mixture of dimethylcarbonate and ethylene carbonate. By this means, in a secondary battery cell comprising, for example, a Li.sub.1+x Mn.sub.2 O.sub.4 positive electrode and a graphite negative electrode, up to about 90% of the theoretical level of lithium can be reversibly cycled at an exceptionally high rate of about C/1 (complete discharge in one hour).

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.