Patent · US Expired

Process for improving enantiomeric purity of aldehydes

US5430194A · kind A · utility

23Cited by
3References
15Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJun 24, 1994
Grant dateJul 4, 1995
Priority date
Expiry dateJun 24, 2014

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/582
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

The present invention relates to a process for producing an optically active aldehyde (first aldehyde) containing a reduced amount of the corresponding enantiomeric aldehyde (second aldehyde) which process comprises: (1) providing an initial solution containing a non-eutectic mixture of the first aldehyde and the second aldehyde, which mixture has a composition in the compositional region where only the first aldehyde crystallizes when its solubility limit in the solution is exceeded, and (2) maintaining the solution at a temperature above the eutectic temperature of the mixture and under conditions such that the solubility limit of the first aldehyde is exceeded so as to form a crystalline first aldehyde containing relatively less of the second aldehyde than was present in the initial solution.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.