Patent · US Expired

Treatment of spent refinery caustic

US5434329A · kind A · utility

5Cited by
8References
15Claims
0Family size

Assignee

Inventor

Key dates

Filing dateJun 25, 1993
Grant dateJul 18, 1995
Priority date
Expiry dateJun 25, 2013

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C7/14841
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A hydrocarbon stream is washed with caustic solution to reactively remove hydrogen sulfide and produce a spent caustic solution containing sulfide reaction products. The spent caustic solution is stripped with concentrated carbon dioxide to reactively remove the sulfides and produce an overhead hydrogen sulfide stream and a bicarbonate-containing bottoms stream. The hydrogen sulfide stream can be converted to elemental sulfur in a Claus unit or to sulfuric acid in a sulfuric acid plant. The bicarbonate solution can be washed with liquid hydrocarbon to remove mercaptans and phenols in further preparation for disposal.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.