Patent · US Expired

Photochromic substituted naphthopyran compounds

US5466398A · kind A · utility

178Cited by
14References
22Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJun 21, 1993
Grant dateNov 14, 1995
Priority date
Expiry dateJun 21, 2013

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07D311/92
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Described are novel reversible photochromic 3H-naphtho[2,1-b]pyran compounds, of the following graphic formula: ##STR1## wherein R.sub.1 is hydrogen or alkyl, R.sub.2 is hydrogen or preferably a carboalkoxy group and R.sub.3 is hydrogen or preferably an alkyl group, provided that either R.sub.1 or R.sub.2 is hydrogen, and B and B' are the aryl groups phenyl or naphthyl, a heterocyclic aromatic group or together form a spiro adamantylene group. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., spiro(oxazine) type compounds, are also described.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.