Patent · US Expired

Process for producing a propylene block copolymer

US5468810A · kind A · utility

78Cited by
7References
15Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJul 26, 1994
Grant dateNov 21, 1995
Priority date
Expiry dateJul 26, 2014

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S526/901
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A propylene block copolymer having a high rigidity and an excellent impact strength is produced by (1) first polymerizing propylene or a mixture of propylene and another ethylenically unsaturated hydrocarbon monomer in the presence of a catalyst comprising a Ti-containing solid component (A), an organic Al compound-containing component (B) and an alkoxyl silicon compound-containing component (C), and (2) second copolymerizing, in a gas phase, propylene and another ethylenically unsaturated hydrocarbon monomer in the presence of the first crystalline polymer of step (1) by re-using the catalyst of first polymerization, and in the presence of a saturated hydrocarbon with 6 or more carbon atoms, thereby forming an elastomeric fraction incorporated into the crystalline polymeric fraction.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.