Preparation of 4,4'-dihydroxy-alpha'-dialkylstilbenes and 4, 4'-dihydroxy-alpha'-dialkylstilbenes
US5475155A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jan 18, 1995 |
| Grant date | Dec 12, 1995 |
| Priority date | — |
| Expiry date | Jan 18, 2015 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07C37/20
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
4,4'-Dihydroxy-alpha-alkylstilbenes of high purity are prepared by reacting at a temperature of from about -20.degree. C. to about 20.degree. C. a mixture of (1) at least one alpha-haloketone, (2) at least one phenolic hydroxyl-containing compound or alkoxy-containing aromatic compound, and (3) at least one strong protonic acid or Lewis acid; such that the mole ratio of phenolic hydroxyl-containing compound or alkoxy-containing aromatic compound:alpha-haloketone(s) is from 0.1:1 to 1.9:1, and the mole ratio of phenolic hydroxyl-containing compound or alkoxy-containing aromatic compound:alpha-haloketone(s):strong protonic acid or Lewis acid is from about 0.1:1:0.0026 to about 1.9:1:0.95. The high purity 4,4'-dihydroxy-alpha-alkylstilbenes are useful for the advancement of epoxy resins, for the preparation of phenoxy resins and for the preparation of epoxy resins.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.