Patent · US Expired

Desulfurization of hydrocarbon streams

US5482617A · kind A · utility

34Cited by
10References
25Claims
0Family size

Assignee

Inventors

Key dates

Filing dateAug 8, 1994
Grant dateJan 9, 1996
Priority date
Expiry dateAug 8, 2014

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC10G45/28
  • WIPO fieldBasic materials chemistry
  • WIPO sectorChemistry

Abstract

A process for desulfurizing a hydrocarbon stream which includes at least 50 ppmw sulfur in the form of organic sulfur compounds, and C.sub.5 + hydrocarbons including benzene. The hydrocarbon stream is contacted in the absence of added hydrogen with a fluidized bed of an acidic catalyst having a structure of ZSM-5, ZSM-11, ZSM-22, ZSM-23, ZSM-35, ZSM-48, MCM-22, MCM-36, MCM-49, zeolite Y, zeolite beta or mixtures thereof to convert the organic sulfur compounds to hydrogen sulfide. The catalyst contacts the hydrocarbon stream at a pressure of from 0.0 psig to about 400 psig, a temperature of from about 400.degree. F. to about 900.degree. F., and a weight hourly space velocity of from about 0.1 hr..sup.-1 to about 10.0 hr..sup.-1. Thereafter, the hydrogen sulfide is removed from the hydrocarbon stream.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.