Patent · US Expired

Copper-impregnated zeolite composition

US5488020A · kind A · utility

3Cited by
69References
17Claims
0Family size

Assignee

Inventors

Key dates

Filing dateFeb 23, 1994
Grant dateJan 30, 1996
Priority date
Expiry dateFeb 23, 2014

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C2601/16
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A composition comprising a copper(I) impregnated aluminosilicate zeolite wherein the zeolite is selected from faujasites, L and .OMEGA., and wherein the zeolite has a silica to bulk alumina molar ratio between about 12 and about 50 and a silica to framework alumina molar ratio of at least about 15. The catalyst preparation involves in the following order: drying the selected zeolite, impregnating the dried zeolite with a copper(II) salt, calcining the copper(II)-impregnated zeolite, and reducing the copper(II) to copper(I). The composition is useful as a catalyst for the cyclodimerization of 1,3-butadiene to 4-vinylcyclohexene.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.