Preparation of polymers of C.sub.2 -C.sub.10 -alk-1-enes using racemic metal-locene complexes as catalysts

US5491205A · kind A · utility

Assignee

• BASF SE

Inventors

• Franz Langhauser · Bad Dürkheim, DE
• Jurgen Kerth · Eisenberg (Pfalz), DE
• Gunther Schweier · Osthofen, DE
• Hans-Herbert Brintzinger · Frauenfeld, CH
• Stefan Mansel · Konstanz, DE
• Werner Roell · Konstanz, DE
• Robin Kirsten · Stockach, DE

Key dates

• Filing date: Oct 28, 1994
• Grant date: Feb 13, 1996
• Expiry date: Oct 28, 2014

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C08F4/63927
• WIPO field: Macromolecular chemistry, polymers
• WIPO sector: Chemistry

Abstract

Polymers of C.sub.2 -C.sub.10 -alk-1-enes are prepared at from 0.5 to 3000 bar and from -50.degree. to 300.degree. C. using a catalyst system by a process in which the catalyst system used is one which contains, as active components: a) a metallocene complex of the general formula I ##STR1## where M is titanium, zirconium, hafnium, vanadium, niobium or tantalum, X is fluorine, chlorine, bromine, iodine, hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl or --OR.sup.7, PA1 R.sup.7 is C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl, alkylaryl, arylalkyl, fluoroalkyl or fluoraryl, where each alkyl radical is of 1 to 10 carbon atoms and each aryl radical is of 6 to 20 carbon atoms, R.sup.1 to R.sup.6 are each hydrogen, C.sub.1 -C.sub.10 -alkyl, 5-membered to 7-membered cycloalkyl, which in turn may carry C.sub.1 -C.sub.10 -alkyl radicals as substituents, C.sub.6 -C.sub.15 -aryl or arylalkyl, where two adjacent radicals together may furthermore be a cyclic group of 4 to 15, carbon atoms, or Si(R.sup.8).sub.3 R.sup.8 is C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl or C.sub.3 -C.sub.10 -cycloalkyl, is silicon, germanium, tin or carbon, Y.sup.1, Y.sup.2 are each ##STR2## R.…