Patent · US Expired

Radiation-curable silicone-release compositions with high and controlled release values

US5494945A · kind A · utility

9Cited by
14References
12Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMay 11, 1995
Grant dateFeb 27, 1996
Priority date
Expiry dateMay 11, 2015

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10T428/31663
  • WIPO fieldBasic materials chemistry
  • WIPO sectorChemistry

Abstract

A radiation-curable silicone release composition is described which comprises (A) a mixture of organopolysiloxanes characterized by the formul a EQU RSi(CH.sub.3).sub.2 --O--(Si(CH.sub.3).sub.2 O).sub.n (Si(CH.sub.3)(R)O).sub.m Si(CH.sub.3).sub.2 R (I) wherein the mixture comprises (A-1) from about 25% to 95% by weight of at least one organopolysiloxane characterized by Formula I wherein each R is --R.sup.1 --O(O)C--C(R.sup.2).dbd.CH.sub.2, R.sup.1 is a hydrocarbylene group, R.sup.2 is hydrogen or a methyl or ethyl group, m is a number from about 1 to about 15, and n is a number from about 50 to about 300, and (A-2) from about 5% to 75% by weight of at least one other organopolysiloxane characterized by Formula I wherein R is --R.sup.1 --OCH.sub.2 CH(OH)--CH.sub.2 O(O)C--C(R.sup.2).dbd.CH.sub.2, R.sup.1 is a hydrocarbylene group, R.sup.2 is hydrogen or a methyl or ethyl group, m is a number from about 1 to about 25, and n is a number from about 50 to about 300, and (B) from 0% to about 5% by weight of a photoinitiator. A method of producing silicone release-coated substrates, the release-coated articles thus produced, and multi-layer articles or constructions incorporating a silico…

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.