Method of forming a stable form of LiMnO.sub.2 as cathode in lithium cell
US5506078A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Apr 26, 1995 |
| Grant date | Apr 9, 1996 |
| Priority date | — |
| Expiry date | Apr 26, 2015 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02E60/10
- WIPO fieldElectrical machinery, apparatus, energy
- WIPO sectorElectrical engineering
Abstract
The invention disclosed relates to a new method of forming spinel-related .lambda.-Li.sub.2-x Mn.sub.2 O.sub.4, wherein 0.ltoreq.x.ltoreq.2, solely by electrochemical means with air-stable orthorhombic LiMnO.sub.2 as the starting material. This spinel-related material is hydroscopic, metastable and is typically made by chemical means, followed by electrochemical conversion of spinel-type LiMn.sub.2 O.sub.4. Also disclosed are new secondary lithium ion electrochemical cells employing as initial active cathode material a compound of formula LiMnO.sub.2, having a specific orthorhombic crystal structure.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.