Patent · US Expired

Elecrolyte for a secondary cell

US5529859A · kind A · utility

37Cited by
4References
14Claims
0Family size

Assignee

Inventors

Key dates

Filing dateApr 15, 1994
Grant dateJun 25, 1996
Priority date
Expiry dateApr 15, 2014

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02E60/10
  • WIPO fieldElectrical machinery, apparatus, energy
  • WIPO sectorElectrical engineering

Abstract

A conventional electrolyte for a secondary cell having a carbonaceous anode is comprised of an alkali metal salt dissolved in an organic electrolyte solvent. Intercalation and de-intercalation during repeated discharge/charge cycles of the secondary cell using a conventional electrolyte solvent causes continual exposure of bare surfaces of the carbonaceous material to the electrolyte, resulting in continual consumption of electrolyte in the formation of new passivation films on the bared or partially covered surfaces, adversely affecting the performance and capacity of the cell. In accordance with the present invention, at least a portion of the organic electrolyte solvent is replaced with a chloroethylene carbonate solvent capable of forming a very stable passivation film. The performance and capacity of the secondary cell is improved substantially by the addition of the halogenated organic solvent to propylene carbonate.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.