Process for preparing aromatic hydroxycarboxylic acids
US5532406A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | May 19, 1994 |
| Grant date | Jul 2, 1996 |
| Priority date | — |
| Expiry date | May 19, 2014 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07C51/15
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
A process for preparing aromatic hydroxycarboxylic acids or di-salts thereof by reaction of alkali metal phenolates or naphtholates with carbon dioxide, in the presence or absence of a further alkali metal salt, which comprises introducing the solid phenolate or naphtholate starting materials and, if desired, the alkali metal salt into the reaction mixture batchwise or continuously, separately or together, in the form of a dispersion in an inert organic liquid. The process of the invention makes possible the preparation of aromatic hydroxycarboxylic acids in good yields and with high chemical selectivity. Additional measures for increasing the selectivity, as are described for the Kolbe-Schmitt reaction in, for example, EP-A 0 053 824, EP-A 0 081 753 and EP-A 0 254 596, can be omitted.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.