Process for the two-stage hydrogenation of methyl esters
US5536889A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Sep 29, 1995 |
| Grant date | Jul 16, 1996 |
| Priority date | — |
| Expiry date | Sep 29, 2015 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC12C11/02
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
This invention relates to a process for the two-stage hydrogenation of methyl esters which comprises: a) contacting and reacting one or more detergent range methyl esters with hydrogen under predominantly liquid phase hydrogenation conditions at a temperature of less than about 230.degree. C., in the presence of a catalyst comprising a copper compound, a zinc compound, and at least one compound selected from the group consisting of aluminum, zirconium, magnesium, a rare earth and mixtures thereof, to produce an alcohol product and a wax ester product, and b) contacting and reacting the wax ester product from step a) with hydrogen under predominantly liquid phase hydrogenation conditions at a temperature greater than about 220.degree. C. in the presence of a catalyst comprising a copper compound, a zinc compound, and at least one compound selected from the group consisting of aluminum, zirconium, magnesium, a rare earth and mixtures thereof, to produce an alcohol product.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.