Unsaturated ethylene-non conjugated diene copolymers and preparation thereof by radical polymerization

US5539075A · kind A · utility

Assignee

• Borealis A/S · DK

Inventors

• Bill Gustafsson · Stenungsund, SE
• Torbj orn Magnusson · Stenungsund, SE
• Kari Alha · Kerava, FI
• Peter Rydin · Skara, SE

Key dates

• Filing date: Apr 21, 1994
• Grant date: Jul 23, 1996
• Expiry date: Apr 21, 2014

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C08F210/18
• WIPO field: Macromolecular chemistry, polymers
• WIPO sector: Chemistry

Abstract

The invention concerns an unsaturated ethylene copolymer, a method for producing the ethylene copolymer, and the use of the ethylene copolymer in compositions for producing cross-linked structures, such as material for electric cables. In the method, ethylene and at least one monomer which is copolymerizable with ethylene and includes a polyunsaturated comonomer having a chain of at least 8 carbon atoms and at least 2 non-conjugated double bonds, of which at least one is terminal, are polymerized at a pressure of about 100-300 MPa and a temperature of about 80.degree.-300.degree. C. under the action of a radical initiator. The polyunsaturated comonomer preferably is an .alpha.,.omega.-alkadiene having 8-16 carbon atoms, most preferred 1,9-decadiene. Apart from the polyunsaturated comonomer, polymerization may also involve another vinyl-unsaturated monomer, preferably containing at least one functional group selected from hydroxyl groups, alkoxy groups, carbonyl groups, carboxyl groups and ester groups. The ethylene copolymers produced have an increased degree of unsaturation, which can be used for cross-linking the ethylene copolymer or grafting reactive groups.