Patent · US Expired

Rechargeable lithium cell and process for making an anode for use in the cell

US5545468A · kind A · utility

96Cited by
4References
13Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMar 16, 1994
Grant dateAug 13, 1996
Priority date
Expiry dateMar 16, 2014

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P70/50
  • WIPO fieldElectrical machinery, apparatus, energy
  • WIPO sectorElectrical engineering

Abstract

A rechargeable lithium cell comprises a cathode having a discharge potential not less than 2 V relative to a Li/Li.sup.+ anode, an anode capable of doping and un-doping lithium and made of a material comprising a lithium titanate having a spinel structure and represented by the general formula, LixTiyO.sub.4 wherein 0.8.ltoreq.x.ltoreq.1.4 and 1.6.ltoreq.y.ltoreq.2.2, a separator separating the cathode and the anode from each other, and an electrolytic solution impregnated at least in the separator and dissolving a lithium salt in a non-aqueous solvent. When subjected to X-ray diffraction analysis, the material has peaks at least at 4.84.+-.0.02 angstroms, 2.53.+-.0.02 angstroms, 2.09.+-.0.02 angstroms and 1.48.+-.0.02 angstroms and a ratio of a peak intensity at 4.84.+-.0.02 angstroms and a peak intensity at 1.48.+-.0.02 angstroms of 100:30.+-.10. The material may consist of the lithium titanate or mixed crystals of the lithium titanate and rutile-type titanium dioxide. A process for making the anode is also described.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.