Patent · US Expired

Oxidation of dimercaptans to organic disulfide polymers

US5545714A · kind A · utility

3Cited by
5References
23Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMay 25, 1995
Grant dateAug 13, 1996
Priority date
Expiry dateMay 25, 2015

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/582
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A process for preparing an organic disulfide polymer such as polyethylene disulfide which is used in batteries comprises contacting a dimercaptan such as 1,2-ethanedithiol with elemental sulfur using a mixture of a basic compound such as NaOH and an ethoxylated alcohol such as Union Carbide's TERGITOL.RTM. 15-S-7 having the formula of R.sup.2 O(CH.sub.2 CH.sub.2 O).sub.7 H as catalyst wherein the dimercaptan is present in excess amount to effect the preparation of the disulfide polymer.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.