Patent · US Expired

Process for the conversion of lower alcohols to higher branched oxygenates

US5559275A · kind A · utility

31Cited by
9References
15Claims
0Family size

Assignee

Inventor

Key dates

Filing dateFeb 21, 1995
Grant dateSep 24, 1996
Priority date
Expiry dateFeb 21, 2015

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C29/34
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A process is provided for the production of branched C.sub.4+ oxygenates from lower alcohols such as methanol, ethanol, propanol and mixtures thereof. The process comprises contacting the lower alcohols with a solid catalyst comprising a mixed metal oxide support having components selected from the group consisting of oxides of zinc, magnesium, zirconia, titanium, manganese, chromium, and lanthanides, and an activation metal selected from the group consisting of Group VIII metal, Group IB metals, and mixtures thereof. The advantage of the process is improved yields and selectivity to isobutanol which can subsequently be employed in the production of high octane motor gasoline.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.