Substituted superconductive Bi-Sr-Ca-Cu oxide and Bi-Sr-Ca-Ln-Cu oxide compositions
US5565414A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Nov 21, 1994 |
| Grant date | Oct 15, 1996 |
| Priority date | — |
| Expiry date | Nov 21, 2014 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S505/784
- WIPO fieldMaterials, metallurgy
- WIPO sectorChemistry
Abstract
A metal oxide is provided which is represented by the compositional formula : EQU (Bi.sub.1-x A.sup.I.sub.x).sub.2 (Sr.sub.y Ca.sub.1-y-z A.sup.II.sub.z).sub.p (Cu.sub.1-r A.sup.III.sub.r).sub.q O.sub..delta. PA1 wherein 0.ltoreq.x.ltoreq.0.5, 0.3.ltoreq.y.ltoreq.0.7, 0.ltoreq.z.ltoreq.0.5, 0.ltoreq.r.ltoreq.0.1, 1>y+z, 2>p>11, 1.ltoreq.q.ltoreq.10 and 5.4.ltoreq..delta..ltoreq.24 with the exclusion of x=z=r=0, A.sup.I is at least one element selected from In, Sb, Pb and Sn; A.sup.II is at least one element selected from Na, K, Mg, Ba, and Sn and A.sup.III is at least one element selected from Ti, V, Cu, Ni, Zr, Nb, Ta, Fe and Ru. The metal oxide may further comprise an element selected from lanthanoids and yttrium. The metal oxide material shows superconductivity at a temperature not lower than the boiling point of liquid helium.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.