Long life NA/NiCl.sub.2 cells
US5573873A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Aug 16, 1994 |
| Grant date | Nov 12, 1996 |
| Priority date | — |
| Expiry date | Aug 16, 2014 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02E60/10
- WIPO fieldElectrical machinery, apparatus, energy
- WIPO sectorElectrical engineering
Abstract
The premature capacity failure of Ni/NiCl.sub.2 secondary cells due to agglomeration of nickel particles on the surface of the NiCl.sub.2 cathode is prevented by addition of a minor amount, such as 10 percent by weight of a transition metal such as Co, Fe or Mn to the cathode. The chlorides of the transition metals have lower potentials than nickel chloride and chlorinate during charge. A uniform dispersion of the transition metals in the cathodes prevents agglomeration of nickel, maintains morphology of the electrode, maintains the electrochemical area of the electrode and thus maintains capacity of the electrode. The additives do not effect sintering. The addition of sulfur to the liquid catholyte is expected to further reduce agglomeration of nickel in the cathode.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.