Patent · US Expired

Low surface energy polyisocyanates and their use in one-or two component coating compositions

US5576411A · kind A · utility

11Cited by
8References
16Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 14, 1994
Grant dateNov 19, 1996
Priority date
Expiry dateSep 14, 2014

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08G18/8054
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

The present invention is directed to a polyisocyanate mixture PA0 i) having an NCO content of 5 to 35% by weight and prepared from an organic diisocyanate, PA0 ii) containing at least 1% by weight of isocyanurate groups (calculated as N.sub.3, C.sub.3, O.sub.3, MW 126), PA0 iii) containing allophanate groups in an amount such that there are more equivalents of allophanate groups than urethane groups and PA0 iv) containing fluorine (calculated as F, AW 19) in an amount of 0.001 to 50% by weight, wherein the preceding percentages are based on the solids content of the polyisocyanate mixture, excluding any unreacted organic diisocyanate, and wherein fluorine is incorporated by reacting an isocyanate group with a compound containing two or more carbon atoms, one or more hydroxyl groups and one or more fluorine atoms to form urethane groups and converting a sufficient amount of these urethane groups to allophanate groups to satisfy the requirements of iii), provided that the polyisocyanate mixture contains sufficient allophanate groups to ensure that the polyisocyanate mixture remains stable and homogeneous in storage for 3 months at 25.degree. C. The present invention is also directed …

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.