Patent · US Expired

Method and silicate composition for conditioning silica surfaces

US5578179A · kind A · utility

23Cited by
1References
18Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJul 12, 1995
Grant dateNov 26, 1996
Priority date
Expiry dateJul 12, 2015

Classification

  • Technology area (CPC G)Physics
  • CPC primaryG01N2030/285
  • WIPO fieldMeasurement
  • WIPO sectorInstruments

Abstract

Disclosed is a method for increasing the electro-osmotic flow rate available for a silica surface. In the method, there is provided an electrophoretic channel which is defined by one or more silica surfaces. The surface(s) are contacted with an alkaline aqueous solution containing a solubilized silicate-monovalent metal complex in an amount effective to increase the acidity of the silica surface(s), as evidenced by a reduction in the average bulk pKa of the surface(s). The achieved increase in acidity is greater than would be obtained using an otherwise identical solution lacking said silicate. In one preferred embodiment, the monovalent metal used in the solution is Li.sup.+, Na.sup.+, or K.sup.+. Also disclosed is a method for increasing the acidity of a silica surface, by contacting the surface with an alkaline aqueous solution of the type noted above.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.