Patent · US Expired

Binary ferrihydrite catalysts

US5580839A · kind A · utility

23Cited by
5References
16Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 30, 1994
Grant dateDec 3, 1996
Priority date
Expiry dateSep 30, 2014

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC10G1/086
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A method of preparing a catalyst precursor comprises dissolving an iron salt and a salt of an oxoanion forming agent, in water so that a solution of the iron salt and oxoanion forming agent salt has a ratio of oxoanion/Fe of between 0.0001:1 to 0.5:1. Next is increasing the pH of the solution to 10 by adding a strong base followed by collecting of precipitate having a binary ferrihydrite structure. A binary ferrihydrite catalyst precursor is also prepared by dissolving an iron salt in water. The solution is brought to a pH of substantially 10 to obtain ferrihydrite precipitate. The precipitate is then filtered and washed with distilled water and subsequently admixed with a hydroxy carboxylic acid solution. The admixture is mixed/agitated and the binary ferrihydrite precipitate is then filtered and recovered.

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