Patent · US Expired

Fluorinated polymers and copolymers containing cyclic structures

US5589557A · kind A · utility

16Cited by
15References
9Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMay 15, 1995
Grant dateDec 31, 1996
Priority date
Expiry dateMay 15, 2015

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C43/313
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Polymers and copolymers of one or more fluorinated dienes of structure CFX.sup.1 .dbd.CX.sup.2 --O--CX.sup.3 X.sup.4 --O--CX.sup.2 .dbd.CX.sup.1 F, wherein X.sup.1 and X.sup.2 are F, Cl or H, and X.sup.3 and X.sup.4 are F or CF.sub.3, wherein said dienes essentially form cyclic repetitive units, the comonomers used for preparing copolymers being ethylene unsaturated fluorinated compounds. Processes for preparing the fluorinated dienes having said structure which comprise the reaction in solution between one halogenated olefin and one hypofluorite CX.sup.3 X.sup.4 (OF).sub.2, wherein X.sup.3 and X.sup.4 are F or CF.sub.3, and the dehalogenation or dehydrohalogenation of the linear adduct between one hypofluorite molecule and two olefin molecules. The polymers and copolymers of the invention are particularly suitable for preparing coatings for applications at high temperatures.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.