Process for selective hydrogenation of highly unsaturated compounds and isomerization of olefins in hydrocarbon streams
US5595634A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jul 10, 1995 |
| Grant date | Jan 21, 1997 |
| Priority date | — |
| Expiry date | Jul 10, 2015 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S203/06
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
A process for treating C.sub.3 to C.sub.12 petroleum fractions, such as a light cracked naphtha to be used as an etherification feed stock in which H.sub.2 S is removed by distillation of at least the C.sub.3 fraction and mercaptans and diolefins are removed simultaneously in a distillation column reactor using a dual catalyst bed. The mercaptans and H.sub.2 S are reacted with the diolefins in the presence of a reduced nickel catalyst to form sulfides which are higher boiling than the portion of the feed which is fractionated to an upper hydrogenation catalyst bed of palladium for hydrogenating diolefins and acetylenes. The higher boiling sulfides are removed as bottoms along with heavier materials. Any diolefins not converted to sulfides and acetylenes are selectively hydrogenated to mono-olefins in the presence of a palladium oxide catalyst in an upper bed, producing overheads, substantially free of sulfur compounds, diolefins and acetylenes.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.