Patent · US Expired

Free fall polymerization process for the production of polycarbonates

US5596067A · kind A · utility

5Cited by
4References
11Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 1, 1995
Grant dateJan 21, 1997
Priority date
Expiry dateSep 1, 2015

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S159/10
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A method for producing an aromatic polycarbonate comprises introducing to an introduction zone (having a perforated plate) a) a molten monomer mixture of an aromatic dihydroxy compound and a diaryl carbonate, or b) a molten prepolymer obtained by a process comprising reacting an aromatic dihydroxy compound with a diaryl carbonate, and allowing the monomer mixture or prepolymer in the molten state to pass downwardly through the perforated plate and fall freely through a free-fall polymerization reaction zone, thereby effecting polymerization of the monomer mixture or prepolymer during the free-fall thereof. Colorless and high quality aromatic polycarbonates are thus stably produced at a high polymerization rate for a prolonged period of time, using an apparatus which has excellent sealing properties under high vacuum and maintenance of which is easy.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.