Patent · US Expired

Continuous process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation

US5600048A · kind A · utility

24Cited by
22References
24Claims
0Family size

Assignee

Inventors

Key dates

Filing dateDec 27, 1994
Grant dateFeb 4, 1997
Priority date
Expiry dateDec 27, 2014

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/582
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

There is provided a process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation. The liquid phase alkylation reaction may be catalyzed by an acidic solid oxide, such as MCM-22, MCM-49 and MCM-56. The vapor phase transalkylation may be catalyzed by a medium-pore size zeolite such as ZSM-5. The process may be run continuously with the continuous introduction of fresh benzene feed containing at least 500 ppm of nonbenzene hydrocarbon impurities. The combined ethylbenzene product of these alkylation and transalkylation reactions has very low levels of impurities including xylene, hydrocarbons having 7 or less carbon atoms and hydrocarbons having 9 or more carbon atoms.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.