Imide oligomers and co-oligomers containing pendent phenylethynyl groups and polymers therefrom

US5606014A · kind A · utility

Assignee

• The United States of America as represented by the United States National Aeronautics and Space Administration · US

Inventors

• John W. Connell · Newport News, US
• Joseph G. Smith, Jr. · Smithfield, US
• Paul M. Hergenrother · Yorktown, US

Key dates

• Filing date: Aug 4, 1995
• Grant date: Feb 25, 1997
• Expiry date: Aug 4, 2015

Classification

• Technology area (CPC Y): Emerging Cross-Sectional Technologies
• CPC primary: Y10T428/31721
• WIPO field: Macromolecular chemistry, polymers
• WIPO sector: Chemistry

Abstract

Controlled molecular weight imide oligomers and co-oligomers containing pendent phenylethynyl groups (PEPIs) and endcapped with nonreactive or phenylethynyl groups have been prepared by the cyclodehydration of the precursor amide acid oligomers or co-oligomers containing pendent phenylethynyl groups and endcapped with nonreactive or phenylethynyl groups. The amine terminated amide acid oligomers or co-oligomers are prepared from the reaction of dianhydride(s) with an excess of diamine(s) and diamine containing pendent phenylethynyl groups and subsequently endcapped with a phenylethynyl phthalic anhydride or monofunctional anhydride. The anhydride terminated amide acid oligomers and co-oligomers are prepared from the reaction of diamine(s) and diamine containing pendent phenylethynyl group(s) with an excess of dianhydride(s) and subsequently endcapped with a phenylethynyl amine or monofunctional amine. The polymerizations are carried out in polar aprotic solvents such as under nitrogen at room temperature. The amide acid oligomers or co-oligomers are subsequently cyclodehydrated to the corresponding imide oligomers. The polymers and copolymers prepared from these materials exhibit a…