Etherification--hydrogenation process
US5628880A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Feb 12, 1996 |
| Grant date | May 13, 1997 |
| Priority date | — |
| Expiry date | Feb 12, 2016 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S203/06
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
A process for removing dienes from etherification uses a hydrogenation zone in the reactor distillation column above the etherification zone. MTBE is produced and the unreacted C.sub.4 stream is also subjected to selective hydrogenation of the butadiene contained in the C.sub.4 feed stream. The C.sub.4 stream is first contacted with methanol in the etherification zone where the MTBE is distilled downward. The unreacted C.sub.4 's then are subjected to selective hydrogenation in the hydrogenation zone where butadiene in the overhead raffinate is reduced by over 90%. The hydrotreated C.sub.4 's are thus suitable for cold acid alkylation or other use wherein butadiene is harmful.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.