Patent · US Expired

Star block copolymer of vinylaromatic monomer and of conjugated diene process for preparing it, and its compositions with crystal polystyrene

US5635561A · kind A · utility

3Cited by
7References
10Claims
0Family size

Assignee

Inventor

Key dates

Filing dateMar 4, 1996
Grant dateJun 3, 1997
Priority date
Expiry dateMar 4, 2016

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/582
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

The invention relates to a star block copolymer of the formula [S.sub.1 -S.sub.2 -(B.sub.1 /S.sub.3)-B.sub.2 ].sub.m -X-[B.sub.2 (B.sub.1 /S.sub.3)-S.sub.2 ].sub.n in which X represents a polyfunctional radical resulting from a coupling agent, m and n represent non-zero integers such that m+n is equal to 3 or 4, S.sub.1 and S.sub.2 each represent a block of a polymer containing at least one vinylaromatic monomer, B.sub.2 represents a block of a polymer containing at least one conjugated diene, (B.sub.1 /S.sub.3) represents a block of a statistical copolymer containing at least one vinylaromatic monomer and at least one conjugated diene, 40 to 75% by weight of (B.sub.1 /S.sub.3) consisting of resulting from vinylaromatic monomer, characterized in that the sum of the mass of the blocks B.sub.2 contains more than 40% by weight and less than 90% by weight of the total mass of the conjugated diene contained in the said star block copolymer. The invention also relates to the process for obtaining this copolymer. The compositions comprising this copolymer and crystal polystyrene have noteworthy mechanical properties and transparencies.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.