Patent · US Expired

Method for the preparation of a fluorine-containing organopolysiloxane

US5639845A · kind A · utility

27Cited by
11References
12Claims
0Family size

Assignee

Inventors

Key dates

Filing dateNov 1, 1995
Grant dateJun 17, 1997
Priority date
Expiry dateNov 1, 2015

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08G77/385
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A novel and very efficient method is disclosed for the introduction of perfluoroalkyl groups into an organopolysiloxane by utilizing the hydrosilation reaction with an organohydrogenpolysiloxane. Different from the conventional but inefficient hydrosilation reaction using a perfluoroalkyl-substituted ethylene as the olefin compound, the inventive method utilizes a propene-1 3-substituted by a perfluoroalkyl group compound as the olefin compound to react with an organohydrogenpolysiloxane by which a very high efficiency in the hydrosilation reaction can be obtained without side reactions which otherwise greatly decrease the yield of the desired perfluoroalkyl-containing organopolysiloxane product.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.