Patent · US Expired

Process for the production of 1,1,1-trifluoroethane

US5639924A · kind A · utility

2Cited by
16References
30Claims
0Family size

Assignee

Inventors

Key dates

Filing dateNov 29, 1994
Grant dateJun 17, 1997
Priority date
Expiry dateNov 29, 2014

Classification

  • Technology area (CPC B)Performing Operations; Transporting
  • CPC primaryB01J27/128
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

Process for synthesizing 1,1,1-trifluoroethane (143a) in the gaseous phase by reacting 1,1-defluoro-1-chloroethane in gaseous phase in the presence of a Cr catalyst. The process may be run isothermally or adiabatically, without co-feeding air or other oxygen containing gas, in the presence or absence of a Ni, Co, Zn or Mn cocatalyst for the Cr catalyst. The catalyst may be unsupported or supported with a support preferably selected from activated carbon, alumina and fluorided alumina. The formation of olefin byproduct can be kept to less than 10 ppm in accordance with the process of the invention.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.