Patent · US Expired

Process for the encapsulation and stabilization of radioactive, hazardous and mixed wastes

US5678234A · kind A · utility

22Cited by
18References
14Claims
0Family size

Assignee

Inventors

Key dates

Filing dateNov 7, 1994
Grant dateOct 14, 1997
Priority date
Expiry dateNov 7, 2014

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02W30/91
  • WIPO fieldMaterials, metallurgy
  • WIPO sectorChemistry

Abstract

The present invention provides a method for encapsulating and stabilizing radioactive, hazardous and mixed wastes in a modified sulfur cement composition. The waste may be incinerator fly ash or bottom ash including radioactive contaminants, toxic metal salts and other wastes commonly found in refuse. The process may use glass fibers mixed into the composition to improve the tensile strength and a low concentration of anhydrous sodium sulfide to reduce toxic metal solubility. The present invention preferably includes a method for encapsulating radioactive, hazardous and mixed wastes by combining substantially anhydrous wastes, molten modified sulfur cement, preferably glass fibers, as well as anhydrous sodium sulfide or calcium hydroxide or sodium hydroxide in a heated double-planetary orbital mixer. The modified sulfur cement is preheated to about 135.degree..+-.5.degree. C., then the remaining substantially dry components are added and mixed to homogeneity. The homogeneous molten mixture is poured or extruded into a suitable mold. The mold is allowed to cool, while the mixture hardens, thereby immobilizing and encapsulating the contaminants present in the ash.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.