Oxygen permeable mixed conductor membranes
US5702999A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Dec 10, 1996 |
| Grant date | Dec 30, 1997 |
| Priority date | — |
| Expiry date | Dec 10, 2016 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC01P2006/80
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
The present invention relates to novel solid state mixed conductor membranes and their use for separating oxygen from oxygen-containing feeds at elevated temperatures. The membranes comprise a multicomponent metallic oxide of substantially cubic perovskite structure, stable in air over the temperature range of 25.degree.-950.degree. C., having no connected through porosity wherein the membrane is of a composition represented by the formula A.sub.1-x A'.sub.x !Co.sub.1-y-z B.sub.y B'.sub.z !O.sub.3-.delta., where A.ident.Ca, Sr, Ba, and mixtures thereof; A'.ident.La, Y, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th, U, and mixtures thereof; B.ident.Fe, Mn, Cr, V, Ti, and mixtures thereof; B'.ident.Cu, Ni, and mixtures thereof; .about.0.0001.ltoreq..times..ltoreq..about.0.1; .about.0.002.ltoreq.y<0.05; .about.0.0005.ltoreq.z.ltoreq..about.0.3; .delta. is determined by the valence of the metals.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.