Fluorescent detection of hydrazine, monomethylhydrazine, and 1,1-dimethylhydrazine by derivatization with aromatic dicarboxaldehydes
US5719061A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Oct 20, 1994 |
| Grant date | Feb 17, 1998 |
| Priority date | — |
| Expiry date | Oct 20, 2014 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10T436/173845
- WIPO fieldMeasurement
- WIPO sectorInstruments
Abstract
A method and apparatus for the detection of hydrazine, monomethylhydrazine, 1,1-dimethylhydrazine in air (or other gas medium) or in an aqueous solution. The detection is accomplished by introducing a stream of air, or other gas medium, or aqueous solution suspected of containing hydrazine, monomethylhydrazine, 1,1-dimethylhydrazine or mixtures thereof into a pH controlled reagent solution containing an aromatic dicarboxaldehyde to react with the hydrazine, monomethylhydrazine, 1,1-dimethylhydrazine or mixtures thereof, respectively, and by exposing the reacted reagent solution to an excitation wavelength range and monitoring an emission from the exposed reagent solution at an emission wavelength range to detect the presence of a hydrazine derivative, monomethylhydrazine derivative, 1,1-dimethylhydrazine derivative, or mixtures thereof (i.e. a derivative formed by the reaction between hydrazine, monomethylhydrazine, 1,1-dimethylhydrazine and the aromatic dicarboxaldehyde) indicating the presence of hydrazine, monomethylhydrazine, 1,1-dimethylhydrazine or mixtures thereof within the stream of air or other gas medium or aqueous solution.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.