Optically activate phosphines,their preparation and their metal complexes, and use in asymmetric synthesis
US5723642A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | May 6, 1996 |
| Grant date | Mar 3, 1998 |
| Priority date | — |
| Expiry date | May 6, 2016 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07F15/008
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
Optically active phosphines of the general formula I or II ##STR1## where the variables have the following meanings: X is an optically active terpene radical, PA1 R is an unsubstituted or substituted phenyl radical, PA1 Y is a bridge member having 1-10 C atoms in the formula I PA1 n is 1,2 or 3 and PA1 m is 0,1 or 2 with the proviso that n+m=3 in the formula II PA1 n is 1 or 2 and PA1 m is 0 or 1 with the proviso that n+m=2, their preparation and use are described.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.