Use of reactive distillation in the manufacture of methyl tertiary butyl ether
US5741953A · kind A · utility
Assignee
Inventor
Key dates
| Filing date | Aug 17, 1995 |
| Grant date | Apr 21, 1998 |
| Priority date | — |
| Expiry date | Aug 17, 2015 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/10
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
An aqueous methanol feed stream contaminated with tertiary butyl alcohol is charged to a reactive distillation column having a reaction distillation section in the upper portion thereof containing an acid cation exchange resin and separated therein into a substantially anhydrous lower boiling methanol fraction contaminated with isobutylene and a higher boiling water fraction by charging the feed stream to the lower portion of the reactive distillation column to separate the feed stream into a higher boiling water fraction and a lower boiling methanol fraction containing a tertiary butyl alcohol-water azeotrope for upward flow into the reactive distillation section for reaction of the tertiary butyl alcohol to form isobutylene, MTBE and water and recovery of a substantially anhydrous lower boiling methanol fraction contaminated with isobutylene and MTBE.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.