Patent · US Expired

Occluded composite-particle latex

US5770303A · kind A · utility

17Cited by
8References
13Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJan 5, 1996
Grant dateJun 23, 1998
Priority date
Expiry dateJan 5, 2016

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10T428/31906
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A latex binder composition comprises occluded composite particles containing at least a vinyl ester homopolymer or a copolymer thereof polymerized from acrylate and/or ethylene monomers, and a polymer polymerized from conjugated diene and/or vinyl substituted aromatic monomers and desirably unsaturated carboxylic acid monomers. The occluded composite particles are produced in the absence of crosslinking agents by first polymerizing the vinyl esters and optional acrylate and/or ethylene monomers, and subsequently in situ polymerizing the conjugated diene and/or vinyl substituted aromatic, etc., monomers in the presence of the vinyl ester latex particles. The occluded composite-particle latex contains phase separated domains which are neither a core-shell nor an inverted core-shell particle and provide properties which are superior to physical blends of the two classes of polymers when utilized as binders in paper coating formulations. Such properties include excellent ink receptivity, low mottle, good blister resistance, good coating strength, good brightness, and the like.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.