Patent · US Expired

Regeneration of severely deactivated reforming catalysts

US5776849A · kind A · utility

27Cited by
8References
21Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 9, 1992
Grant dateJul 7, 1998
Priority date
Expiry dateSep 9, 2012

Classification

  • Technology area (CPC B)Performing Operations; Transporting
  • CPC primaryB01J2229/42
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

The invention is directed a process for regenerating deactivated reforming catalysts comprising at least one Group VIII metal on zeolite L, preferably wherein the catalysts are extruded using a binder material such as alumina or silica. The process includes: a) coke burn at severe conditions to improve the accessibility of the Group VIII catalytic metal particles by transporting them to the outside of the zeolite microchannels; b) catalytic metal redispersion by wet oxychlorination with elemental chlorine and oxygen; c) stripping with a gas stream comprising oxygen and water at low pressure to remove as much residual chlorine as possible; and d) reduction of catalytic metals with hydrogen at low pressure. The process is particularly effective for recovering activity of catalysts which have been severely deactivated.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.