Diphosphines bonded to side chains of polymers, and metal complexes thereof
US5777062A · kind A · utility
Assignee
Inventor
Key dates
| Filing date | Feb 23, 1996 |
| Grant date | Jul 7, 1998 |
| Priority date | — |
| Expiry date | Feb 23, 2016 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08G18/836
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
The invention relates to polymers having structural repeating units of at least one monomer MM which contains a hydroxyl group or a primary or secondary amine group as a functional group bonded directly or in a side chain, wherein the functional group is bonded via a bridge group Q formed by a diisocyanate to the hydroxyl group or primary or secondary amino group of an aliphatic, cycloaliphatic, heterocycloaliphatic, aromatic or heteroaromatic ditertiary diphosphine, the phosphine groups of which are bonded to a carbon chain in the 1,2-, 1,3-, 1,4- or 1,5-position relative to one another. The invention also relates to a process for their preparation and to rhodium and iridium complexes with these diphosphine ligands. Using these rhodium and iridium complexes, optically pure compounds which are valuable intermediates for the preparation of biologically active ingredients, in particular in the field of pharmaceuticals and agrochemicals, can be obtained in a hydrogenation process which is likewise according to the invention. Thus, for example, it is possible to prepare from secondary amines, in particular N-carbalkoxymethylamines, 5-imidazolecarboxylic acid derivatives which have a he…
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.