Patent · US Expired

Preparation of double metal cyanide-catalyzed polyols by continuous addition of starter

US5777177A · kind A · utility

56Cited by
12References
19Claims
0Family size

Assignee

Inventor

Key dates

Filing dateFeb 7, 1996
Grant dateJul 7, 1998
Priority date
Expiry dateFeb 7, 2016

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08G2110/0083
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

Double metal cyanide-catalyzed polyols are made by an improved process in which a starter is continuously added during polymerization of the epoxide. The process includes a continuously added starter (S.sub.c), and optionally, an initially charged starter (S.sub.i). The continuously added starter comprises at least about 2 equivalent percent of the total starter used. The process enables the use of water and low molecular weight polyol starters in DMC-catalyzed polyol synthesis. In addition, the process gives polyether polyols having reduced levels of high molecular weight polyol tail, which can adversely affect polyurethane foam processing.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.