Patent · US Expired

Photocatalytic oxidation of organics using a porous titanium dioxide membrane and an efficient oxidant

US5779912A · kind A · utility

85Cited by
14References
44Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJan 31, 1997
Grant dateJul 14, 1998
Priority date
Expiry dateJan 31, 2017

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02W10/37
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A method and apparatus for mineralizing organic contaminants in water or air provides photochemical oxidation in a unique two-phase or three-phase boundary system formed in each pore of a TiO.sub.2 membrane in a photocatalytic reactor. In the three-phase system, gaseous oxidant, liquid contaminant, and solid semiconductor photocatalyst meet and engage in an efficient oxidation reaction. The porous membrane has pores which have a region wherein the meniscus of the liquid varies from the molecular diameter of water to that o f a capillary tube resulting in a diffusion layer that is several orders of magnitude smaller than the closest known reactors. The photocatalytic reactor operates effectively at ambient temperature and low pressures.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.