Patent · US Expired

Porous inorganic oxide materials prepared by non-ionic surfactant templating route

US5795559A · kind A · utility

83Cited by
10References
50Claims
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Key dates

Filing dateMay 2, 1996
Grant dateAug 18, 1998
Priority date
Expiry dateMay 2, 2016

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC01P2006/16
  • WIPO fieldMaterials, metallurgy
  • WIPO sectorChemistry

Abstract

A method for the preparation of new semi-crystalline, porous inorganic oxide compositions possessing uniform framework-confined mesopores in the range 2.0-10.0 nm. The method uses an interaction between various nonionic polyethylene oxide based surfactants (N.degree.) and neutral inorganic oxide precursors (I.sup..quadrature.) at ambient reaction temperatures. The materials formed exhibit a disordered assembly of worm-like channels of regular diameter owing to the specific mechanism of self-assembly, producing highly stable materials and particles incorporating large numbers of the channels. This (N.degree. I.degree.) templating approach introduces several new concepts to mesostructure synthesis. The application of the low-cost, non-toxic and biodegradable surfactants and ambient reaction temperatures, introduces environmentally clean synthetic techniques to the formation of mesostructures. Recovery of the template can be achieved through solvent extraction where the solvent may be water or ethanol.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.