Rubber devulcanization process
US5798394A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Oct 21, 1996 |
| Grant date | Aug 25, 1998 |
| Priority date | — |
| Expiry date | Oct 21, 2016 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02W30/62
- WIPO fieldOther special machines
- WIPO sectorMechanical engineering
Abstract
A process for devulcanizing and functionalizing a rubber vulcanizate by desulfurization involves suspending a rubber vulcanizate crumb in a solvent which preferably swells the rubber vulcanizate before or during the devulcanization reaction and adding an alkali metal, such as sodium, to the suspension. The alkali metal cleaves mono-, di- and polysulfidic cross-linkages in the rubber vulcanizate to liberate rubber polymer having a molecular weight substantially equal to that of the rubber polymer prior to vulcanization. Functional groups derived from the solvent molecules bond to the devulcanized rubber's polymeric backbone. In addition to the functionalized devulcanized rubber polymer, carbon black may also be recovered for re-use in accordance with the process of the present invention. The functionalized devulcanized rubber may be subjected to a re-vulcanization reaction without separation of rubber polymer from the solvent by addition of an appropriate curing mixture.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.