Process for the manufacture of halo esters of carboxylic or dicarboxylic acids
US5804687A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jan 22, 1996 |
| Grant date | Sep 8, 1998 |
| Priority date | — |
| Expiry date | Jan 22, 2016 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07C67/11
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
A compound (Ia) or (Ib) is prepared by reacting, in a polar aprotic solvent, a compound (III) with a salt of a carboxylic or dicarboxylic acid (IIa) or (IIb). The reaction may be carried out under pressure, but also at normal atmospheric pressure or in the region of normal atmospheric pressure (especially between 0.10 bar and 2 bars). The product (Ia) or (Ib) formed is, in this latter case, recovered continuously as it is formed. ##STR1## R.sup.1, R.sup.2 =optionally substituted saturated or unsaturated acyclic or cyclic hydrocarbon radicals; R.sup.3 =C.sub.1 -C.sub.10 perhaloalkyl; 0<n.ltoreq.4; X=halogen. The applications of the fluoroalkyl (meth)acrylates obtained are especially: anti-dust or anti-soiling paints for various supports such as exterior coatings and metal furniture; optical fibers; contact lenses; lithography; electrophotography; heat-resistant materials; dental resins.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.