Nitrate-free method for manufacturing a blue glass composition
US5807417A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jul 11, 1997 |
| Grant date | Sep 15, 1998 |
| Priority date | — |
| Expiry date | Jul 11, 2017 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S501/905
- WIPO fieldMaterials, metallurgy
- WIPO sectorChemistry
Abstract
The invention is nitrate-free method to manufacture a blue soda-lime-silica glass composition and improving the ultraviolet light absorption thereof while maintaining a high visible light transmission. The method comprises the steps of: adding colorants, during molten glass formation, consisting essentially of a manganese compound along with a cobalt compound, iron oxide and optionally titanium oxide to a soda-lime-silica base glass composition, and adding no sodium nitrate into the batch during molten glass formation, the materials are adding in quantities sufficient to form said blue glass composition having at a 4.0 mm. thickness: 477-494 dominant wavelength and 6-40% purity of excitation. The blue glass composition, by weight, comprises a base glass composition of: 68 to 75% SiO.sub.2, 10 to 18% Na.sub.2 O, 5 to 15% CaO, 0 to 10% MgO, 0 to 5% Al.sub.2 O.sub.3, and 0 to 5% K.sub.2 O, where CaO+MgO is 6 to 15% and Na.sub.2 O+K.sub.2 O is 10 to 20%; and colorants consisting essentially of: 0.4 to 2.0% total iron oxide as Fe.sub.2 O.sub.3, 0.15 to 2.00% manganese oxide as MnO.sub.2 ; 0.005 to 0.025% cobalt oxide as Co, and 0 to 1.00% titanium oxide as TiO.sub.2. The glass is useful…
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.