Patent · US Expired

BF.sub.3 gas recovery process

US5811616A · kind A · utility

79Cited by
12References
10Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJun 13, 1995
Grant dateSep 22, 1998
Priority date
Expiry dateJun 13, 2015

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/584
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

BF.sub.3 is vaporized from specified crude polyolefin reaction product mixture in a vaporization zone at a temperature insufficient to decompose BF.sub.3 or any BF.sub.3 promoter complex in the mixture, and the vaporized BF.sub.3 may be recovered directly. Further, a process for the oligomerization of a liquid olefin composition and recovery of BF.sub.3 is described in which inert volatile material present in a liquid olefin composition is removed from the composition by vaporization, forming a degassed liquid olefin composition free of inert volatile material. The degassed liquid olefin composition is then contacted in a reaction zone with BF.sub.3 under conditions to oligomerize the olefin, forming crude polyolefin oligomerization reaction product mixture containing dissolved BF.sub.3, which may be treated as described.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.