Recovery of catalyst systems from diarylcarbonate-containing reaction mixtures by melt crystallization
US5824816A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Apr 1, 1997 |
| Grant date | Oct 20, 1998 |
| Priority date | — |
| Expiry date | Apr 1, 2017 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/584
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
Catalyst systems with a content of a platinum-group-metal catalyst, a co-catalyst, a quaternary salt and a base for the oxidative carbonylation of aromatic hydroxy compounds to the corresponding diaryl carbonates are obtained according to the invention as a residual melt by melt crystallization and can be returned into the carbonylation reaction or worked up to valuable materials. The melt crystallizate, which consists predominantly of diaryl carbonate and the parent aromatic hydroxy compound, is worked up to pure diaryl carbonate and pure hydroxy compound.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.