Method of promoting the activity of solid strong acid catalysts
US5837641A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jan 16, 1996 |
| Grant date | Nov 17, 1998 |
| Priority date | — |
| Expiry date | Jan 16, 2016 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S502/514
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
A method of continuously promoting the activity of solid strong acid catalysts used in acid catalyzed reactions by adding or generating water in the reaction mixture has been developed. The solid strong acid catalyst may be a sulfated metal oxide, a tungstated metal oxide, or a molybdated metal oxide. The metal oxides are oxides, hydroxides, oxyhydroxides, or oxide-hydrates of Group IV-A, Group III-A, Group III-B, and Group V-A metals. The catalyst may also contain a Group VIII metal, or when the metal oxide is a hydroxide, oxide, oxyhydroxide, or oxide-hydrate of the Group IV-A, Group III-A, or Group III-B metals, the catalyst may also contain an oxide, hydroxide, oxyhydroxide or oxide-hydrate of a Group V-A, Group V-B, Group VI-B, or Group VII-B metal as a promoter. The acid catalyzed reactions where the activity promotion method may be applied include catalytic cracking, catalytic reforming, hydrodesulfurization, isomerization, alkylation of aliphatic and aromatic hydrocarbons, polymerization, and oligomerization. The amount of water added to or generated in the reaction mixture may be from about 0.1 ppm to about 500 ppm water.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.