Patent · US Expired

Supported zeolite membranes with controlled crystal width and preferred orientation grown on a growth enhancing layer

US5871650A · kind A · utility

75Cited by
30References
26Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJul 8, 1994
Grant dateFeb 16, 1999
Priority date
Expiry dateJul 8, 2014

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S977/721
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

The present invention is directed toward a new zeolite membrane which exhibits a columnar cross-sectional morphology and preferred crystallographic orientation comprising a porous substrate having coated thereon a mesoporous growth enhancing layer and a layer of columnar zeolite crystals on said mesoporous growth enhancing layer, and wherein said mesoporous growth enhancing layer comprises nanocrystalline or colloidal sized zeolites, nanocrystalline or colloidal zeolite and metal oxide, or nanocrystalline or colloidal zeolite and colloidal metal, or nanocrystalline or colloidal zeolite, colloidal metal and metal oxide, and wherein said mesoporous growth enhancing layer has interstices of about 20 to about 2000 .ANG., and wherein said columnar zeolite layer is a polycrystalline layer wherein 99.9% of said columnar zeolite crystals have at least one point between adjacent crystals that is .ltoreq.20 .ANG.. The invention is further directed to a process of producing a zeolite membrane exhibiting a columnar crystallographic orientation.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.